Gb. Mckenna, ON THE PHYSICS REQUIRED FOR PREDICTION OF LONG-TERM PERFORMANCE OF POLYMERS AND THEIR COMPOSITES, Journal of research of the National Institute of Standards and Technology, 99(2), 1994, pp. 169-189
The long term performance of polymers and their composites is an impor
tant aspect of their increasing use in engineering applications. Tempo
ral, thermal, and mechanical stresses can all contribute to the deteri
oration of performance. Here we examine the concepts of the physics of
glassy polymers and how they are important in developing constitutive
equations that describe their volume/temperature/stress time response
. The understanding of such response forms the basis of the prediction
of long term performance.