F. Debuyck et al., CORRELATION BETWEEN THE THICKNESS AND THE SPECIFIC MASS OF AN ANODIZATION LAYER ON ALUMINUM AND THE MEASURED CURRENT TRANSIENT, Materials chemistry and physics, 38(2), 1994, pp. 169-174
For anodizing of aluminium in a sulphuric acid (15 mass%) solution at
constant voltage, the current initially jumps to a high value and decr
eases rapidly to a low value in the first few seconds; thereafter the
current rises to a constant level. The course of the current versus ti
me is common for all applied voltages and temperatures. However, the h
igher the voltage and temperature are, the faster and higher the rise
and constant level will be. The shape of this current-time curve is re
presentative for the specific anodization layer. Exponential relations
has been found for the different characteristic points (minimum, maxi
mum and steady-state current and the corresponding times) of the curre
nt density-time curve versus voltage and temperature. Also for the thi
ckness and the apparent specific mass of the oxide layer, exponential
functions versus voltage and temperature were found. In this work it h
as been proved that a correlation exists between the measured steady-s
tate current density, the thickness and the apparent specific mass of
the layer. For the formed oxide layers the measured mean real specific
mass value is the same as that one which has already been published.