Se. Schulz et al., ENHANCED RELIABILITY OF W-ENCAPSULATED ALSI-INTERCONNECTIONS USING SELECTIVE W-CVD, Microelectronic engineering, 33(1-4), 1997, pp. 113-120
Reliability of Al based interconnections can be enhanced by using refr
actory metal base and top layers. Therefore encapsulation of Al alloy
lines by selective W-CVD was examined with respect to electromigration
stability. The selective W-CVD was performed in a commercial cluster
tool with a specially equipped selective W-CVD chamber and a high vacu
um load lock. The deposition process was based on the silane reduction
of WF6, which takes place preferentially on electron donating materia
ls (metals, silicides, TiN, etc.). Different pretreatments were examin
ed with respect to their influence on selectivity and nucleation behav
iour at the surface (top and sidewall) of AISI lines. Optimized pretre
atment combinations (HF dip; HF dip + H-2 plasma) resulted in selectiv
e growth of tungsten and uniform encapsulation of the lines. Electromi
gration tests were performed on 2 mu m and 3 mu m wide NIST structures
. The determined mean times to failure (MTF) are up to 7 times larger
compared to conventional AISI interconnections depending on W thicknes
s. The evolution of resistance during an EM test shows that void forma
tion takes place in the Al alloy. In this case current flow can be mai
ntained by the encapsulation layer due to the high electromigration re
sistance of tungsten.