To characterize blanket CVD copper films several analytical tests were
carried out. The impurity concentrations were detected by secondary i
on mass spectroscopy. Values lower than 0.2 at.% were found. Furthermo
re some structural properties like grain sizes were investigated using
transmission electron microscopy. The grain sizes were determined by
TEM dark field images. The model by Mayadas and Shatzkes [1] will be d
iscussed for the explanation of the higher resistivity of CVD deposite
d copper films compared to the bulk value. It was found that the grain
boundaries mainly contribute to this increased resistivity.