Nuclear decay induced Cl-37 ion desorption from the electron capture d
ecay Ar-37-->Cl-37+nu is reported for the first time. A mixture of one
part Ar-36 and approximately 5X10(-5) parts Ar-37 (Ar-36/37) is physi
sorbed on a gold-plated Si wafer kept at 16 K under ultrahigh vacuum c
onditions. The time of flight (TOF) of recoiled Cl-37 ions is measured
using coincidence techniques. The observed kinetic energy distributio
n of the Cl-37 ions is approximately Gaussian in shape, with a maximum
at almost-equal-to 9.0 eV and a full width at half-maximum of approxi
mately 3 eV. Considering the binding energy of physisorbed Ar-37 is ap
proximately 80 meV, the 9-eV peak energy compares well with that of th
e gas-phase value, where conservation of the energy and momentum fixes
the kinetic energy of Cl-37 ions at 9.54 eV. Using a combination of T
OF and retarding field energy analysis, the charge states of detected
ions for 1 ML (monolayer) of Ar-36/37 are determined as 53%+1e, 21%+2e
, and 26%+ne, where n greater-than-or-equal-to 3. The fraction of deca
ying Ar-37 atoms which emerge from the surface as positive Cl-37 ions
is found to be 10%. Finally, a strong charge exchange reaction between
a Cl-37 ion and near-neighbor atoms causes a Coulomb explosion within
the multilayers, increasing the kinetic energy of desorbing ions by a
s much as approximately 7 eV.