Msr. Subrahmanyam et al., ESTIMATION OF THE SHARMA CONSTANT AND THERMOACOUSTIC PROPERTIES OF VEGETABLE-OILS, Journal of the American Oil Chemists' Society, 71(8), 1994, pp. 901-905
The density and volume of four Indian edible vegetable oils, sunflower
, rice bran, groundnut and coconut, and one Indian nonedible oil, cast
or oil, have been experimentally determined. The values obtained were
used to estimate the volume expansivity alpha, hence the thermoacousti
c parameters, such as the Sharma constant S-0, the isochoric temperatu
re coefficient of internal pressure [dlnPi/dlnT](V), the isochoric tem
perature coefficient of volume expansion [dlna/dlnT]V-,V- reduced volu
me ($) over tilde V, reduced compressibility ($) over tilde beta and t
he Huggins parameter F. The results obtained show that the Sharma cons
tant S-0 has the same characteristic value of 1.11 +/- 0.01 for the fi
ve oils, thus establishing the constancy of the Sharma parameter. All
the other parameters are of the expected order of magnitude; however,
in all cases there is a uniform deviation at 293 degrees K, which can
be attributed to the behavior of density and volume at this temperatur
e.