In this article, a continuous stabilization process was used to make f
lame resistant fibers from polyacrylonitrile (PAN) fibers. The effect
of the stabilization time and the stretching process during the stabil
ization process on the physical properties and flammability of the res
ultant flame resistant fibers was studied. Increased drawing of PAN fi
bers during the continuous stabilization process was found to decrease
the diameter and increase the tensile strength in the resultant flame
resistant fibers. These fibers also had higher density. There were no
absolute relationships seen between flame-resistance and the formatio
n of stable ladder polymers, density, and oxygen content.