We investigate the effect of objective-lens chromatic aberration on qu
antitative chemical microanalysis using electron energy-loss spectrome
try in the electron microscope. Experimental tests were done on a spec
imen with a planar interface under the condition of a rather large chr
omatic error in image mode. We discuss three different models of image
formation with inelastically scattered electrons. Simulations for Ni
show that the quantum-mechanical image theory for large defocus values
is practically equivalent to a Lorentzian image distribution and desc
ribes the experimental data satisfactorily. A method to obtain a prope
r defocus setting for the compensation of the chromatic error is also
presented.