Pp. Apte et Kc. Saraswat, CORRELATION OF TRAP GENERATION TO CHARGE-TO-BREAKDOWN (QBD) - A PHYSICAL-DAMAGE MODEL OF DIELECTRIC-BREAKDOWN, I.E.E.E. transactions on electron devices, 41(9), 1994, pp. 1595-1602
Ultrathin gate and tunnel oxides in MOS devices are subjected to high-
field stress during device operation, which degrades the oxide and eve
ntually causes dielectric breakdown. Oxide reliability, therefore, is
a key concern in technology scaling for ultra-large scale integration
(ULSI). Here we provide critical new insight into oxide degradation (a
nd consequently, reliability) by a systematic study of five technologi
cally relevant parameters, namely, stress-current density, oxide thick
ness, stress temperature, charge-injection polarity (gate versus subst
rate), and nitridation of pure oxide. For all five parameters, a stron
g correlation has been observed between oxide degradation and the gene
ration of new traps (distinct from the filling of intrinsic traps). Fu
rther, we observe that this correlation is independent of the trap pol
arity (positive versus negative). Based on this correlation, and based
on the fundamental link between electronic properties and atomic stru
cture, a physical-damage model of dielectric breakdown has been propos
ed. The concept of the physical-damage model is that the oxide suffers
dielectric breakdown when physical damage due to broken bonds forms a
defect-filled filamentary path in the oxide, that conducts excessive
current. A good monitor of this physical damage is trap generation, wh
ich we believe is caused by physical bond breaking in the oxide and at
the interface. The model has been quantified empirically by the corre
lation between trap generation and Q(bd).