The present paper describes the first chemically amplified negative-to
ne resist for deep X-ray lithography (DXRL). The choice of the resist
material for this new resist has been oriented on the experience of th
e photo, electron beam and X-ray lithography (XRL) for microelectronic
applications. In this work a negative tone resist containing a novola
k, a crosslinker and an acid generator was developed by variing the di
fferent components. It was found that only few components, which prove
d to be good in thin films, were suitable for DXRL. The new resist ful
fills all technological requirements and shows an increased sensitivit
y by a factor 15 as compared to the standard resist material, poly(met
hyl methacrylate). This tremendous increase in sensitivity leads to a
huge cost reduction of the DXRL process. Furthermore, an excellent adh
esion of this new resist to metallic substrates has been achieved whic
h allows to fabricate free standing columns with an aspect ratio of 80
.