Z. Benamara et B. Gruzza, PREPARATION AND ESCA ANALYSIS OF THE GERMANIUM SURFACE - ELECTRICAL CHARACTERIZATION OF THE AL2O3 GE AND AL2O3-GEO2/GE STRUCTURES/, Materials chemistry and physics, 39(1), 1994, pp. 85-89
The preparation of the (100) structure of germanium is a crucial step
in the realization of electronic components. Chemical and thermal trea
tments were used in order to obtain samples with reproducible physical
properties. Thin films of GeOx were obtained by thermal oxidation. Su
rface analysis was performed using electron spectroscopy for chemical
analysis (ESCA). Results show the growth of oxide film (thickness 30 a
ngstrom) with a GeO2-like composition. It is also possible to remove t
he native germanium oxide with a chemically controlled process. In add
ition, two kinds of structures, Al2O3/Ge and Al2O2:GeO2/Ge, were prepa
red and characterized electrically. It was found that the germanium ox
ide layer can protect the surface during the deposition of alumina usi
ng an electron gun evaporation set. In this case, the density of defec
ts was greatly reduced.