High quality Ga0.5In0.5P layers were grown by chemical beam epitaxy (C
BE) using tertiarybutylphosphine (TBP) instead of the more conventiona
l phosphine (PH3) gaseous source. It is shown that the use of TBP lead
s to a significant decrease, by at least one decade, of the carbon inc
orporation in the epilayers. All-gaseous source CBE GaAs/Ga0.5In0.5P h
eterojunction bipolar transistors (HBTs) have been grown and character
ized for the first time. TBP grown HBT structure exhibit superior DC g
ain current (beta = 80) when compared with similar PH3 grown structure
s (beta = 20).