We grow by molecular beam epitaxy and study by low temperature photolu
minescence and high resolution electron microscopy pairs of identical
AlAs/GaAs quantum wells, in which an InAs monolayer is inserted at nom
inally symmetric positions in the well, close to one or the other inte
rface. The absolute displacement of indium atoms due to surface segreg
ation processes is studied with respect to the well-defined GaAs/AlAs
interfaces. Both techniques show that the InAs-on-GaAs interface lies
at its nominal position, which gives the first clear example of a kine
tical freezing of segregation processes in semiconductor heterostructu
res. PL data allow us to refine previous estimates of the segregation
efficiency and to compare quantitatively various growth techniques.