We have studied chemical beam epitaxy (CBE) of GaAs by reflection high
-energy electron diffraction (RHEED) and reflectance-difference (RD).
The precursors used are triethylgallium (TEG) and tertiarybutylarsine
(TBA). From the period of the RHEED oscillations the growth rate as a
function of the temperature has been obtained. However, in spite of ex
cellent RHEED oscillations no unambiguous oscillatory behaviour in the
corresponding RD data was resolved. During pure TEG exposure of the G
aAs surface characteristic RD features have been obtained and found re
lated to specific RHEED reconstructions. Furthermore, a study has also
been made of how excess Ga, accumulated on the surface during extende
d TEG exposure, is consumed by subsequent TBA injection.