Phase equilibria in the part of the ternary system Y2O3-Na2O-P2O5, whi
ch contains the composition range YPO4-Na4P2O7-NaPO3, have been examin
ed and determined by differential thermal analysis and X-ray powder di
ffraction. The partial system YPO4-Na4P2O7-NaPO3 is surrounded by thre
e side binary systems, whose phase diagrams are known. In two of these
side systems, there are intermediate compounds with the formulae Na5P
3O10 and Na2YP3O10. It was discovered that in the partial system YPO4-
Na4P2O7-NaPO3 under investigation there are two sections. Their phase
diagrams have been determined as well.