SUPERIONIC CONDUCTION IN THE GLASSY AGI-AG2O-CRO3 SYSTEM - GLASS-FORMATION AND INFRARED-ABSORPTION STUDIES

Authors
RANI AND HARIHARAN K
Citation
And. Rani et K. Hariharan, SUPERIONIC CONDUCTION IN THE GLASSY AGI-AG2O-CRO3 SYSTEM - GLASS-FORMATION AND INFRARED-ABSORPTION STUDIES, Materials chemistry and physics, 33(3-4), 1993, pp. 260-265
Citations number
12
Categorie Soggetti
Material Science
Journal title
Materials chemistry and physics → ACNP
ISSN journal
02540584
Volume
33
Issue
3-4
Year of publication
1993
Pages
260 - 265
Database
ISI
SICI code
0254-0584(1993)33:3-4<260:SCITGA>2.0.ZU;2-8
Abstract
Superionic conduction in the amorphous AgI-Ag2O-CrO3 electrolyte syste m has been studied. The glass-former-to-modifier ratio and the concent ration of AgI were varied continuously to establish the glass-forming domain of the system. X-ray diffraction and differential scanning calo rimetry were used as sensitive probes. Transport studies and infrared absorption spectroscopy were used to characterise xAgI-(100-x)(Ag2O-Cr O3) glasses to help clarify the conduction process and the possible st ructural units of these electrolytes.