A. Katz et al., TI PT/AU-SN METALLIZATION SCHEME FOR BONDING OF INP-BASED LASER-DIODES TO CHEMICAL-VAPOR-DEPOSITED DIAMOND SUBMOUNTS/, Materials chemistry and physics, 33(3-4), 1993, pp. 281-288
A layered structure (consisting of Ti(100 nm)/Pt(200 nm)/Au(500 nm) an
d Au-Sn (2.5 mum total in multiple alternating layers)) was studied as
a bonding scheme for InP-based laser diodes to chemical vapor deposit
ed (CVD) diamond substrates. This structure provided a molten Au-Sn la
yer of eutectic composition (80:20 wt.%) on top of the Ti/Pt adhesion
and barrier metals for about 6 s in the temperature range 300-350-degr
ees-C and allowed for efficient bonding of the device to the substrate
. Longer heating durations allowed a reaction between the Pt and Sn to
consume significant amounts of Sn from the solder, thus elevating its
melting temperature and resolidifying the solder. With optimum bondin
g conditions, a high-quality bond of the InP-based laser diode to the
CVD diamond substrate was observed, and the electrical performance of
the diode was superior to that of diodes that were bonded with the sta
ndard In/BeO configurations.