The cadmium-rich region of the semi-magnetic semiconductor Cd-Fe-Se ph
ase diagram has been partially determined, for the first time, by x-ra
y diffraction techniques and by metallurgical microscopy. The maximum
solid solubility of iron in CdSe, employing annealing techniques, has
been found in this work to be about 19 at. % at 925-degrees-C, while t
he solid solubility limit is generally discussed to be about 12 at. %.
The CdFeSe system appears to be a pseudo-binary one. Further consider
ations about the structure of this system are discussed.