A. Roux et al., THERMAL-RADIATION AND LOW-TEMPERATURE-VAPOR GROWTH OF HGI2 CRYSTAL INPRODUCTION FURNACE, Journal of crystal growth, 130(3-4), 1993, pp. 523-532
Heat exchanges in a sealed ampoule in the LTVG (low temperature vapour
growth) furnace have been modelled in order to compute temperature fi
elds and control the growth of HgI2 crystals from vapour phase at low
temperatures. We use a coupled conductive-radiative model to determine
the shapes of the source and the crystal at different equilibrium sta
tes (i.e. without growth rate). The model involves conductivity anisot
ropy in the crystal and radiative exchanges between grey and diffuse s
urfaces (source and crystal interfaces, Pyrex walls), which are consid
ered as opaque. Internal buoyancy effect is not taken into account as
the pressure inside the ampoule is very small. The source temperature
is fixed. For different undercoolings, i.e. for different cold finger
temperatures, the ''equilibrium'' isotherm between the source/gas and
crystal/gas interfaces has been numerically obtained. This ''equilibri
um'' isotherm, which is associated with the stop of the growing proces
s, gives a crystal shape. This shape is compared with experimental res
ults given by the ETH-Zurich group. The model would permit a better un
derstanding and control of the future HgI2 crystal growth experiment.
The computations are performed using a finite element package (FIDAP).