Jp. Noel et al., PHONON-RESOLVED AND BROAD PHOTOLUMINESCENCE IN STRAINED SI1-XGEX ALLOY MBE LAYERS, Journal of electronic materials, 22(7), 1993, pp. 739-743
In the photoluminescence (PL) spectra of Si1-xGex multi-quantum wells
(MQW) grown by conventional solid source molecular beam epitaxy (MBE),
phonon-resolved, near-bandgap transitions due to shallow dopant bound
exciton or free exciton recombination were observed when the well thi
ckness was less than 40-1000 angstrom, depending on x. Increasing the
Si1-xGex well thickness caused the emergence of a broad, unresolved PL
peak approximately 120 meV lower in energy than the expected bandgap
energy. Interstitial-type platelets, less than 15 angstrom in diameter
, were measured by plan view transmission microscopy to occur in densi
ties that correlated well with the intensity of the broad PL peak. A p
latelet density of approximately 10(8) cm-2 per well was sufficient to
completely quench the phonon-resolved PL. Etching experiments reveale
d that within a given MQW, the platelet density is lowest in the first
grown well and progressively increases in subsequent wells with incre
asing strain energy density, indicating that platelet formation is str
ictly a morphological phenomenon and suggesting that a strain relaxati
on mechanism is in effect before the onset of relaxation by misfit dis
location injection.