H. Weishart et al., MORPHOLOGICAL STABILITY DURING GAAS SOLUTION GROWTH - LIQUID-PHASE EPITAXY VERSUS THE TRAVELING HEATER METHOD, Journal of crystal growth, 131(1-2), 1993, pp. 17-31
Experiments are performed by using liquid phase epitaxy and the travel
ling heater method in order to study separately the influence of cryst
allographic orientation, growth rate and spatial temperature gradients
on the morphology of growth faces in solution growth. Liquid phase ep
itaxy, carried out on planar (111) or (100) oriented substrates, illus
trates the effect of crystallographic orientation with misorientations
towards [110]. The travelling heater method, typically showing a curv
ed interface of the [111] oriented seeds, demonstrates the influence o
f temperature gradients at the growth face. Both methods are used to s
tudy the effect of growth rate variations. Morphological stability can
be achieved for growth rates below a critical value. Temperature grad
ients raise this critical value. The critical value decreases, however
, with increasing misorientation of the growth face. The critical grow
th rate reaches a minimum and then increases again for higher misorien
tation.