400 kV high-resolution electron microscopy is used to study the distri
bution of foreign atoms which are present in substitution in a Ni3Al i
ntermetallic compound. The presence of elements heavier than Al can be
detected in the images. It is shown that these elements are located o
n the Al sites. The contrast of atomic columns containing different el
ements is analysed by multislice calculation and image simulation. The
contrast analysis combined with a statistical approach leads to an es
timation of the overall composition which is in agreement with previou
s experimental results.