We report the growth of doped potassium lithium tantalate niobate (KLT
N) crystals and characterization of their physical properties. The top
seeded solution growth method is described. The specifics of a partic
ular KLTN: Cu growth are presented, and the resultant crystal is descr
ibed. The dielectric properties are compared to those of KTN; the addi
tion of lithium is demonstrated to change the character of the phase t
ransitions as well as increase the transition temperature. Phase diagr
ams for the KLTN system are illustrated as a function of lithium and n
iobium concentration.