Reliability of BST (Ba0.7Sr0.3TiO3) capacitors made by using a MOD tec
hnique was studied in terms of TDDB. DLTS analysis revealed peak-shift
toward the lower-temperature side as the degradation goes further. Ob
tained energy level of interfacial states at grain boundaries was 0.75
eV. We found the capture cross section of the level increases after th
e bias-temperature stress. We also found that the larger grain size of
BST film gives longer lifetime. These results suggest that the reliab
ility is to be determined by the interface of grains.