PREPARATION AND CHARACTERIZATION OF METHYL 11-AMINO-(N-P-TOLUENESULFONYL)-9-E-OCTADECENOATE AND METHYL 8-AMINO-(N-P-TOLUENESULFONYL)-9-E-OCTADECENOATE

Authors
HERRON BF BAGBY MO ISBELL TA BYRDWELL WC PLATTNER R WEISLEDER D
Citation
Bf. Herron et al., PREPARATION AND CHARACTERIZATION OF METHYL 11-AMINO-(N-P-TOLUENESULFONYL)-9-E-OCTADECENOATE AND METHYL 8-AMINO-(N-P-TOLUENESULFONYL)-9-E-OCTADECENOATE, Journal of the American Oil Chemists' Society, 74(3), 1997, pp. 229-234
Citations number
20
Categorie Soggetti
Food Science & Tenology","Chemistry Applied
Journal title
Journal of the American Oil Chemists' Society → ACNP
ISSN journal
0003021X
Volume
74
Issue
3
Year of publication
1997
Pages
229 - 234
Database
ISI
SICI code
0003-021X(1997)74:3<229:PACOM1>2.0.ZU;2-A
Abstract
Allylic amination of methyl oleate with bis(N-p-toluenesulfonyl) sulio diimide results in a mixture of methyl 11-amino-(N-p-toluenesulfonyl)- 9-E-octadecenoate and methyl 8-amino-(N-p-toluenesulfonyl)-9-E-octadec enoate in 58% yield. These novel products were isolated and characteri zed by nuclear magnetic resonance,infrared spectroscopy, mass spectrom etry, and melting point. The reaction was analyzed by high performance liquid chromatography and thin-layer chromatography.