R. Singh et al., ENHANCED DIFFUSION AND IMPROVED DEVICE PERFORMANCE USING DUAL SPECTRAL SOURCE RAPID THERMAL-PROCESSING, Journal of electronic materials, 26(12), 1997, pp. 1422-1427
In this study, we used a vacuum ultraviolet (VUV) radiation source in
conjunction with tungsten halogen lamps based rapid thermal processing
(RTP) system. The two light sources were arranged in different config
urations to study the phosphorus diffusion in silicon. The high energy
VUV photons in conjunction with infrared and visible photons resulted
in enhanced diffusion and improved the bulk properties of silicon sub
strate. An improvement in the leakage currents of the diodes made from
VUV irradiated wafers is observed. A qualitative explanation of the r
esults based on the role of high energy photons in RTP is presented. H
igh energy photons from VUV region to about 800 nm results in a decrea
se in the bond dissociation energies of the molecules, since they are
in electronic excited states. Higher activation of dopants and reducti
on in activation energies is observed. The minority carrier lifetime m
easurements show that there is an enhanced phosphorus gettering and ov
erall reduction of the recombination-generation centers in silicon.