S. Friligkos et al., STRUCTURAL CHARACTERIZATION OF ALPHA-SI FILMS CRYSTALLIZED BY COMBINED FURNACE AND LASER ANNEALING, Journal of crystal growth, 182(3-4), 1997, pp. 341-351
Amorphous Si films grown by low-pressure chemical vapor deposition (LP
CVD) were subjected to a two-stage annealing process involving a low-t
emperature furnace annealing at 600 degrees C for 6h followed by laser
annealing under various beam energy densities. The structure of the p
oly-silicon films was studied by means of transmission electron micros
copy (TEM) and atomic force microscopy (AFM). Large, heavily defected
grains are formed during the furnace annealing step, the in-grain defe
cts being mainly microtwins. These defects are eliminated by a combine
d liquid-solid slate process taking place at sufficiently high laser e
nergy densities, whereas the mean grain size remains constant. This pr
ocess occurs up to the critical energy density corresponding to the ne
ar-complete melting of the films. The furnace annealing controls the s
ize of the grains and the subsequent laser annealing the in-grain defe
ct density. The two-step annealing process is far more tolerant compar
ed with the super lateral growth (SLG) method and fully applicable in
large area electronics.