For use as metallization in CMOS device fabrication, we established a
single wafer CVD copper deposition process using CupraSelect(R) (Schum
acher) as a precursor. We utilized a direct liquid injection system in
cluding an HPLC pump. The dependence of film properties upon temperatu
re and pressure is described. The CVD process is suitable for conforma
l filling of 16 mu m deep via holes with an aspect ratio of 8. The mea
sured film resistivity is 1.95 mu Omega cm as deposited and is reduced
to 1.86 mu Omega cm after an annealing step.