M. Irmscher et al., TOP SURFACE IMAGING PROCESS AT AND BELOW QUARTER-MICRON RESOLUTION AND PATTERN TRANSFER INTO METAL, Journal of vacuum science & technology. B, Microelectronics and nanometer structures processing, measurement and phenomena, 15(6), 1997, pp. 2605-2609
The use of top surface imaging processes pushes the limits of both dee
p ultraviolet lithography and e-beam direct writing. However, the flow
effect due to silylation with monofunctional aminosilanes prevents th
e creation of a faithful resist mask of a high resolution. The applica
tion of mixed mono- and bifunctional agents causes crosslinking of the
silylated resist and eliminates the flow, We investigated details of
the silylation of novolak-based chemically amplified resists with a mi
xture of bis(dimethylamino)methylsilane and dimethylsilydiethylamine.
After mixing, new materials evolved until a stable ratio of all compon
ents was reached. During silylation the ratio changes again and requir
es a continuous adaptation of the silylation parameters. The optimized
process enables the realization of a 0.15 mu m pattern in 0.7 mu m th
ick resist. An inductively coupled plasma etcher was evaluated for tra
nsferring of the resulting resist structures into typical aluminium al
loys. The developed process enables the etching of subquarter-micron f
eatures into 0.6 mu m thick AlSiCu layers. (C) 1997 American Vacuum So
ciety.