Recently, it was found that undoped semi-insulating InP can be reprodu
cibly obtained by wafer annealing at 950 degrees C for 40 h under phos
phorus vapor pressure of I atm. Resistivity variation across the 50 mm
diameter wafer after this annealing process, however, was in the rang
e of 22.5-53.7%. In order to realize the fabrication of undoped semi-i
nsulating (SI) InP with uniform electrical properties, multiple-step w
afer annealing (MWA) procedure has been applied for the first time. It
was found that two-step wafer annealing at 950 degrees C for 40 h und
er phosphorus vapor pressure of 1 atm and at 807 degrees C for 40 h un
der phosphorus vapor pressure ranging from 30 to 50 atm, was effective
in improvement of the uniformity of the electrical properties of undo
ped SI InP. By the present MWA, the resistivity variation of 8-12% and
the mobility Variation of 2-4% could be obtained for 50 mm diameter w
afers.