ORDERING PHENOMENA IN ABA TRIBLOCK COPOLYMER GELS

Temperature and concentration dependencies of the degree of order in A BA triblock copolymer gels are discussed. Two factors can influence th e ordering phenomena: the conformation of the midblocks (links of the network) and the polydispersity of the endblock domains (nodes of the network). The latter is defined by the scattering density profile (pol ymer chain packing) at the domain boundary: a sharp boundary correspon ds to less polydisperse domains and to increased order in the arrangem ent of the network nodes. The structure of the network can be describe d in terms of a highly distorted crystalline lattice with close-packed spheres or with cubic (presumably BCC) equilibrium morphology. The ap pearance of the latter is never detected in the gels with a stretched conformation of the midblock.