ZnSe heteroepitaxial layers have been grown on GaAs (100), (110) on ax
is, and (110) 6 degrees miscut substrates by molecular beam epitaxy. Z
nSe on GaAs (110) shows smooth and featureless spectra from Rutherford
backscattering channeling measurements taken along major crystalline
directions, whereas ZnSe on GaAs (100) without pre-growth treatments e
xhibit large interface disorder in channeling spectra. ZnSe films grow
n on GaAs (110) on axis show facet formation over a wide range of grow
th conditions. The use of (110) 6 degrees miscut substrates is shown t
o suppress facet formation; and under the correct growth conditions, f
acet-free surfaces are achieved. Etch pit density measurements give di
slocation densities for ZnSe epitaxial layers grown on GaAs (100), (11
0) on axis, and (110) 6 degrees miscut substrates of 10(7)/cm(2), 3 x
10(5)/cm(2) and 5 x 10(4)/cm(2), respectively. These results suggest t
hat with further improvements to ZnSe growth on GaAs (110)-off substra
tes it may be possible to fabricate defect free ZnSe based laser devic
es.