This paper illustrates the use of attenuated total reflectance (ATR) s
pectra of fruit purees or jams, and diffuse reflectance (DRIFT) spectr
a of jams, to provide the chemical information necessary to check the
composition and authenticity of these products. The fingerprint region
contains information reflecting the carbohydrate, acid, and pectin co
ntent. Although differences between products from different fruit type
s, or between genuine and adulterated samples, can be seen in the spec
tra by eye, the samples cannot be identified unambiguously by visual i
nspection. Statistical methods can aid this identification, however. A
n example of the use of principal component analysis is presented, ena
bling genuine raspberry purees to be distinguished from raspberry pure
es doctored by the addition of sucrose solution to a level of about 6%
sucrose.