FT-IR STUDY OF CRYSTALLINE TETRACHLOROMETALLATES OF CINCHONINE

Citation
A. Weseluchabirczynska et C. Paluszkiewicz, FT-IR STUDY OF CRYSTALLINE TETRACHLOROMETALLATES OF CINCHONINE, Mikrochimica acta, 1997, pp. 265-266
Citations number
7
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00263672
Year of publication
1997
Supplement
14
Pages
265 - 266
Database
ISI
SICI code
0026-3672(1997):<265:FSOCTO>2.0.ZU;2-L
Abstract
FT-IR spectra of cinchoninium tetrachlorocadmate (II) and tetrachloroz incate (II) dihydrate complexes in the 50-650 cm(-1) region were obtai ned and analysed. Normal coordinate calculations of the MX42- moieties in these isomorphous compounds and their bromide analogues were done. The force constants obtained confirm that the geometry of the tetrach lorometallates investigated is strongly influenced by the cinchoninium counter-cation.