THE FOURIER-TRANSFORM INFRARED-SPECTRA OF THE 1 1 ELECTRON DONOR-ACCEPTOR COMPLEXES OF BORON-TRIFLUORIDE WITH DIMETHYL ETHER AND DIMETHYL SULFIDE IN CRYOGENIC MATRICES/

Authors
NXUMALO LM FORD TA
Citation
Lm. Nxumalo et Ta. Ford, THE FOURIER-TRANSFORM INFRARED-SPECTRA OF THE 1 1 ELECTRON DONOR-ACCEPTOR COMPLEXES OF BORON-TRIFLUORIDE WITH DIMETHYL ETHER AND DIMETHYL SULFIDE IN CRYOGENIC MATRICES/, Mikrochimica acta, 1997, pp. 383-385
Citations number
5
Categorie Soggetti
Chemistry Analytical
Journal title
Mikrochimica acta → ACNP
ISSN journal
00263672
Year of publication
1997
Supplement
14
Pages
383 - 385
Database
ISI
SICI code
0026-3672(1997):<383:TFIOT1>2.0.ZU;2-6
Abstract
The infrared spectra of boron trifluoride co-deposited with dimethyl e ther and dimethyl sulphide in nitrogen and argon matrices have been re corded at cryogenic temperatures. The wavenumber shifts of the monomer bands resulting from the formation of 1:1 electron donor-acceptor com plexes have been measured and rationalized on the basis of the interac tions of the Lewis acid (boron trifluoride) with hard (dimethyl ether) and soft (dimethyl sulphide) bases.