This work shows the enhancement of spectral absorptions by noble metal
s (Ag, Au) deposited in nm-thick layers on the surface of ATR-crystals
. By the surface-enhanced infrared absorption (SEIRA) technique, the a
bsorption bands of p-nitrobenzoic acid can be enhanced by a factor of
up to 40. This enables the detection of substance concentrations in th
e mM range. The structure of the metal deposit has been investigated b
y atomic force microscopy and correlated with the enhancement factor.