The microstructures of the Sn-Zn-Al lead-free solders have been invest
igated using scanning electron microscopy. The Al and Zn contents of t
he solders investigated were 0.45%similar to 4.5% and 8.55%similar to
85.5%, respectively. The solders were prepared from the Zn-5Al master
alloy and Sn. The precipitates formed in these solders were analyzed f
or their compositions with energy dispersive spectroscopy. The eutecti
c temperature and the transition temperatures of these solders upon co
oling were identified with cooling curves as well as with differential
scanning calorimetry.