We have systematically studied the structure, chemical composition, an
d formation processes of ZnSe/GaAs(0 0 1) interfaces where heterovalen
cy plays an important role. Prior to ZnSe growth, the initial surfaces
were prepared by exposing differently reconstructed GaAs surfaces to
a beam of Zn, Se, or Te. It has been shown that the structure and the
composition of this interface can be well controlled by the preparatio
n procedures of initial GaAs surfaces. We have also found that generat
ion of the faulted defects in ZnSe films is closely related with the f
ormation of interface layers. (C) 1998 Elsevier Science B.V. All right
s reserved.