Using reflectance difference spectroscopy, we investigate in situ the
interface and surface anisotropies and bonding conditions of molecular
beam epitaxial grown ZnSe and CdTe layers using GaAs (0 0 1) as subst
rate, simultaneously characterized by reflection high-energy electron
diffraction. The thermally cleaned GaAs (0 0 1) surface shows typicall
y a (4 x 6) reconstruction. In this work we tackle the problem of assi
gning spectral features in reflectance difference spectroscopy to spec
ific surface terminations. One major goal is to determine the differen
ce between topmost cation and anion layers. (C) 1998 Published by Else
vier Science B.V. All rights reserved.