ZnSe p-i-n-type photodiodes were grown on GaAs substrates using molecu
lar beam epitaxy technique. ZnCl2 was used for n-doping and plasma-exc
ited N-2 for p-doping. The p-side contact consists of 200 nm Au in sit
u deposited on a 20 nm highly doped ZnTe layer on top of the p-doped Z
nSe forming a well-defined Schottky barrier, as can be confirmed by cu
rrent-voltage measurements together with an electrical model of the di
ode. Reverse-bias photocurrent was measured as a function of wavelengt
h. The spectral responsivity is about 30 mA/(WeV) at the band edge whi
ch corresponds to a quantum efficiency of roughly 8%. Calculations of
the spectral response were performed using a modified model originally
designed on Si solar cells and reflectivity data determined by ellips
ometry. The comparison of the model with measurements indicates that t
he photocurrent is dominated by the drift current generated within the
space-charge region. (C) 1998 Published by Elsevier Science B.V. All
rights reserved.