High quality ZnSe(100) substrates have been used for homoepitaxial gro
wth by molecular beam epitaxy. A chemical pretreatment suitable for Zn
Se substrate preparation is determined from x-ray photoemission spectr
oscopy studies. Thermal cleaning processes for the ZnSe(100) surface w
ere investigated by insitu reflection high energy electron diffraction
and the surface phase diagram for ZnSe(100) was obtained for the firs
t time. The low temperature photoluminescence spectra recorded from ho
moepitaxial layers exhibit unsplit free and bound exciton transitions
with strong intensities. The full widths at half maximum of the (400)
x-ray diffraction spectra for ZnSe homoepitaxial layer were 17 similar
to 31 arcsec.