REDRAWN PHASE-SEPARATED BOROSILICATE GLASSES - A TEM INVESTIGATION

Two alkali aluminoborosilicate glasses containing oriented crystalline particles have been investigated by Transmission Electron Microscopy (TEM). Both materials have been thermally treated in order to phase-se parate crystalline droplets and have been then redrawn at a temperatur e above their softening point to elongate and orient them. In one samp le the crystalline phase is a Ag(Cl, Br) solid solution, which gives t he material birefringence properties, while in the other sample the pa rticles on the surface have been chemically reduced to Ag, giving the material polarizing properties (Polarcor (TM)). Most of the observed n eedle-like particles are built up by a small number of well grown crys tallites often separated by voids. Both the crystallites and the voids occupy the whole width of the particles and can assume very different lengths. Crystallites inside a particle have different orientations.