R. Menzel et al., MASKLESS SUB-MU-M PATTERNING OF SILICON-CARBIDE USING A FOCUSED ION-BEAM IN COMBINATION WITH WET CHEMICAL ETCHING, Journal of vacuum science & technology. B, Microelectronics and nanometer structures processing, measurement and phenomena, 16(2), 1998, pp. 540-543
Two methods for maskless patterning of SiC using a focused Ga+ beam an
demonstrated: the enhancement of the chemical etching rate by amorphi
zation of c-SiC to a-SiC and physical sputtering if deep structures ar
e required. Both methods are followed by wet chemical etching in HF:HN
O3 =1:1 at 80 degrees C to remove the remaining a-SiC. Assuming the cr
itical displacement density for amorphization to be about the same as
for the onset of etching, the measured depths of the structures were c
ompared with the depths of amorphization estimated with TRIM 87 calcul
ations. To find optimum sputtering parameters the energy dependence of
the sputter yield was investigated and compared with TRIM 87 simulati
ons, too. Damage after implantation and after wet chemical etching was
investigated by means of Raman spectroscopy. No damaged material rema
ining after wet chemical etching could be detected. (C) 1998 American
Vacuum Society. [S0734-211X(98)05402-X].