Hs. Kim et al., GATE OXIDE RELIABILITIES IN MOS (METAL-OXIDE-SEMICONDUCTOR) STRUCTURES WITH TI-POLYCIDE GATES, Journal of electronic materials, 27(4), 1998, pp. 21-25
We have investigated the thermal degradation of gate oxide in metal-ox
ide-semiconductor (MOS) structures with Ti-polycide gates. We found th
at the Ti-diffusion into the underlying polysilicon and consequently t
o the gate oxide occurs upon thermal cycling processes, which results
in the dielectric breakdown of the gate oxide. We also found that the
Ti-diffusion is suppressed by the employment of the thin (about 5 nm)
titanium nitride (TiN) diffusion barrier layer, which consequently imp
roved the reliability characteristics of gate oxide significantly.