The theoretical minimum thermal conductivity can be used to model heat
transport in a wide variety of bulk and thin-film materials with stro
ng atomic-scale disorder. To explore the possibility of using metastab
le microstructures in thin-film materials to achieve significant reduc
tions in conductivity, we present experimental results-obtained using
the 3 omega method in the temperature range 77-400 R-on two novel syst
ems. (I) The thermal conductivity of a low-dielectric-constant ''flowa
ble oxide'' (HSiO1.5, hydrogen silsesquioxane) is greatly reduced rela
tive to SiO2. (2) The thermal conductivity of stabilized zirconia /SiO
2 mrdtilayms is unchanged by solid-solid interfaces separated by nanom
eter length scales.