E. Ishida et al., ULTRA-SHALLOW BOX-LIKE PROFILES FABRICATED BY PULSED ULTRAVIOLET-LASER DOPING PROCESS, Journal of vacuum science & technology. B, Microelectronics and nanometer structures processing, measurement and phenomena, 12(1), 1994, pp. 399-404
Ultra-shallow, boxlike impurity profiles are produced using gas immers
ion laser doping (GILD) and then analyzed by spreading resistance prof
ilometry (SRP) and secondary ion mass spectrometry (SIMS) to determine
the impurity distribution. At high concentrations, the profiles obtai
ned by SRP exhibit the expected boxlike shape over the entire range of
junction depths: The measured concentration within the junction regio
n is uniform while the dopant gradient at the junction exceeds 1 decad
e/5 nm. In comparison, the same profiles analyzed using high primary i
on energy SIMS show a broader transition at the metallurgical junction
. Caused by knock-ons and ion mixing during the sputtering process, th
e inaccuracy is markedly reduced by lowering the acceleration energy o
f the primary Cs+ ion beam. At lower concentrations (<10(19)/cm3), pro
files analyzed by SRP exhibit shallower junctions than expected. Elect
rical measurements of diodes and Hall structures show that high-qualit
y, ultra-shallow n+p, np, and pn junctions are fabricated with good do
se control using GILD. For complete characterization of GILD, accurate
measurement of both chemical and electrically active dopant profiles
are required. At present, neither SIMS nor SRP provides an entirely ac
curate impurity profile.