R. Sporken et al., ZNSE ZNSXSE1-X HETEROJUNCTION VALENCE-BAND DISCONTINUITY MEASURED BY X-RAY PHOTOELECTRON-SPECTROSCOPY/, Journal of electronic materials, 27(6), 1998, pp. 776-781
X-ray photoelectron spectroscopy was used to measure the valence band
discontinuity at the ZnSe/ZnSxSe1-x interface as a function of alloy c
omposition. Due to the large lattice mismatch, the experimental values
have to be corrected in order to account for strain in the ZnSe layer
s. We find the valence band discontinuity to vary between 0 and 0.76 e
V as a function of S content x. This result is in excellent agreement
with theoretical calculations. It also shows that the conduction band
discontinuity is not negligibly small.