I. Mizushima et al., ULTRA-HIGH DOSE BORON ION-IMPLANTATION - SUPERSATURATION OF BORON ANDITS APPLICATION, Materials chemistry and physics, 54(1-3), 1998, pp. 54-59
Super-saturation of dopant atoms in silicon has been attracting intere
st because a high concentration of carriers in silicon is required in
practical applications and is scientifically important. A high hole co
ncentration of about 1 x 10(21) cm(-3) is obtained by implanting boron
into silicon substrate with a dose of 1 x 10(17) cm(-2). In such supe
r-saturated boron in silicon, it was found that the clustered boron at
oms (B-12) substitute silicon atoms. The results of a first-principles
calculation indicated that the icosahedral boron cluster is energetic
ally preferable to the cube-octahedral cluster. As a practical applica
tion, low resistivity contact between aluminum and silicon of lower th
an 1 x 10(-8) Omega cm(2) was demonstrated by this high dose boron imp
lantation technique with co-implantation of germanium. (C) 1998 Elsevi
er Science S,A. All rights reserved.