We report the initial growth stage of GaN film on sapphire substrate b
y hot-wall epitaxy (HWE) technique. Roughness of the substrate surface
for high-quality GaN film deposition can be controlled by the initial
ly nitridated layers. We form the nitridated layer on a sapphire (0 0
0 1) surface under the ambient ammonia gas and the substrate temperatu
re of 1050 degrees C. The initial layers are grown on the nitridated l
ayer. The GaN epilayers are grown on the initial layer and their opto-
electronic properties are examined. The photoluminescence characterist
ics of GaN epilayers shows strong band edge emission peaks at 3.474 eV
and very weak emission in the yellow spectral region. Undoped GaN epi
layer grown at around 1 mu m/h shows the carrier concentration of low
10(18) cm(-3) and mobility of up to 50 cm(2)/V s at room temperature.
(C) 1998 Elsevier Science B.V. All rights reserved.