The compensation of Mg-doped GaN is systematically studied by low-temp
erature photoluminescence (PL) using a series of samples with differen
t Mg concentrations. Strongly doped samples are found to be highly com
pensated in electrical measurements. The compensation mechanism is dir
ectly related to the incorporation of Mg. Three different deep donor l
evels are found at 240 +/- 30, 350 +/- 30 and 850 +/- 30 meV from the
conduction band. With increasing excitation density in photoluminescen
ce measurements these levels are subsequently neutralized giving rise
to a Jeep unstructured donor-acceptor pair (DAP) emission. These emiss
ions exhibit a blueshift that saturates at higher densities, thus excl
uding band fluctuations as the prime mechanism for the low energy of t
he observed DAP bands. (C) 1998 Elsevier Science B.V. All rights reser
ved.